Underfill encapsulants prepared from allylated amide compounds

1. An underfill encapsulant comprising an allylated amide compound; a curing initiator selected from the group consisting of a free-radical initiator, a photoinitiator, and a combination of those; optionally, one or more fillers; optionally, one or more adhesion promoters; the allylated amide compound having the formula in m is 0 or 1, n is 1 to 6, and (a) R 9 is H, an alkyl group having 1 to 18 carbon atoms, an alkyleneoxy group having 1 to 18 carbon atoms; aryl, or substituted aryl having the structure in which R 10 , R 11 , and R 12 are independently H or an alkyl or alkyleneoxy group having 1 to 18 carbon atoms; (b) Q is an aromatic group selected from the group of aromatic groups having the structures: (c) Q is selected from the group consisting of in which each R 2 independently is an alkyl, aryl, or arylalkyl group having 1 to 18 carbon atoms; R 3 is an alkyl or alkyloxy chain having up to 100 atoms in the chain, which chain may contain aryl substituents; and X is O, S, N, or P; and v is 0 to 50; (CR 1 2 ) e SiR 4 2 O f SiR 4 2 (CR 1 2 ) g (ii) which the R 1 substituent independently for each position is H or an alkyl group having 1 to 5 carbon atoms, the R 4 substituent independently for each position is an alkyl group having 1 to 5 carbon atoms or an aryl group, e and g are independently 1 to 10, and f is 1 to 50; in which R 3 is an alkyl or alkyloxy chain having up to 100 atoms in the chain, which chain may contain aryl substituents; in which p is 1 to 100, each R 3 independently is an alkyl or alkyloxy chain having up to 100 atoms in the chain, which chain may contain aryl substituents, or R 3 is a siloxane having the structure (CR 1 2 ) e SiR 4 2 O f SiR 4 2 (CR 1 2 ) g in which the R 1 substituent independently for each position is H or an alkyl group having 1 to 5 carbon atoms, the R 4 substituent independently for each position is an alkyl group having 1 to 5 carbon atoms or an aryl group, e and g are independently 1 to 10, and f is 1 to 50; in which p is 1 to 100, each R 3 independently is an alkyl or alkyloxy chain having up to 100 atoms in the chain, which chain may contain aryl substituents, or R 3 is a siloxane having the structure (CR 1 2 ) e SiR 4 2 O f SiR 4 2 (CR 1 2 ) g in which the R 1 substituent independently for each position is H or an alkyl group having 1 to 5 carbon atoms, the R 4 substituent independently for each position is an alkyl group having 1 to 5 carbon atoms or an aryl group, e and g are independently 1 to 10, and f is 1 to 50.

2. An underfill encapsulant comprising an allylated amide compound; a curing initiator selected from the group consisting of a free-radical initiator, a photoinitiator, and a combination of those; optionally, one or more fillers; optionally, one or more adhesion promoters; the allylated amide compound having the formula in which m is 0 or 1, n is 1-6, and (a) R 9 is H, an alkyl or alkyleneoxy group having 1 to 18 carbon atoms, allyl, aryl, or substituted aryl having the structure in which R 10 , R 11 , and R 12 are independently H or an alkyl or alkyleneoxy group having 1 to 18 carbon atoms; (b) K is an aromatic group selected from group of aromatic groups having the structures: in which R 5 , R 6 , and R 7 are a linear or branched chain alkyl, alkyloxy, alkyl amine, alkyl sulfide, alkylene, alkyleneoxy, alkylene amine, alkylene sulfide, aryl, aryloxy, or aryl sulfide species having up to about 100 atoms in the chain, which may contain saturated or unsaturated cyclic or heterocyclic substituents pendant from the chain or as part of the backbone in the chain, and in which any heteratom present may or may not be directly attached to the aromatic ring; or R 5 , R 6 , and R 7 are a siloxane having the structure (CR 1 2 ) e SiR 4 2 O f SiR 4 2 (CH 3 ) g in which the R 1 substituent is H or an alkyl group having 1 to 5 carbon atoms and the R 4 substituent independently for each position is an alkyl group having 1 to 5 carbon atoms or an aryl group, and e is 1 to 10 and f is 1 to 50; and (c) Z is selected from the group consisting of (i) a linear or branched chain alkyl, alkyloxy, alkyl amine, alkyl sulfide, alkylene, alkyleneoxy, alkylene amine, alkylene sulfide, aryl, aryloxy, or aryl sulfide species having up to about 100 atoms in the chain, which may contain saturated or unsaturated cyclic or heterocyclic substituents pendant from the chain or as part of the chain, and in which any heteroatom present may or may not be directly attached to K; in which each R 2 independently is an alkyl, aryl, or arylalkyl group having 1 to 18 carbon atoms; R 3 is an alkyl or alkyloxy chain having up to 100 atoms in the chain, which chain may contain aryl substituents; and X is O, S, N, or P; and v is 0 to 50; (iii) (CR 1 2 ) e SiR 4 2 O f SiR 4 2 (CR 1 2 ) g in which the R 1 substituent independently for each position is H or an alkyl group having 1 to 5 carbon atoms, and the R 4 substituent independently for each position is an alkyl group having 1 to 5 carbon atoms or an aryl group, and e and g are independently 1 to 10 and f is 1 to 50; in which R 3 is an alkyl or alkyloxy chain having up to 100 atoms in the chain, which chain may contain aryl substituents; or in which p is 1 to 100, each R 3 independently is an alkyl or alkyloxy chain having up to 100 atoms in the chain, which chain may contain aryl substituents, or R is a siloxane having the structure (CR 1 2 ) e SiR 4 2 O f SiR 4 2 (CR 1 2 ) g in which the R 1 substituent independently for each position is H or an alkyl group having 1 to 5 carbon atoms, the R 4 substituent independently for each position is an alkyl group having 1 to 5 carbon atoms or an aryl group, e and g are independently 1 to 10, and f is 1 to 50; in which p is 1 to 100, each R 3 independently is an alkyl or alkyloxy chain having up to 100 atoms in the chain, which chain may contain aryl substituents, or R 3 is a siloxane having the structure (CR 1 2 ) e SiR 4 2 O f SiR 4 2 (CR 1 2 ) g in which the R 1 substituent independently for each position is H or an alkyl group having 1 to 5 carbon atoms, the R 4 substituent independently for each position is an alkyl group having 1 to 5 carbon atoms or an aryl group, e and g are independently 1 to 10, and f is 1 to 50.