A method of forming a metal plug, which method has the steps of depositing a metal film on an insulating film after formation of a contact opening in the insulating film and etching the metal film to bury the metal film in the contact opening, includes the steps of forming on the metal film either a smooth tungsten film formed by bias-sputtering, a smooth silicon nitride film formed by competitive reactions as etching and deposition reactions, a smooth resist film or a smoothing layer constituted by an SOG or organic polymer layer on the metal film and etching back the smooth layer or smoothing layer and the metal film under conditions in which etching rates are almost equal to each other so as to smoothly bury the metal film in the contact opening.
Legal claims defining the scope of protection, as filed with the USPTO.
1. A method of forming a metal plug, comprising the steps of: forming a contact opening in an insulating film; depositing a first film on said insulating film and in the contact opening; depositing a second metal film with a rough surface on said first film; forming a smoothing layer on said second metal film; performing a first etching to an entire surface of said first and second films by a radical reaction to remove any portion of the films outside of said contact opening; and then performing a second etching in which a deposition reaction and an etching reaction of said first and second films are competitive reactions to form a metal plug with a smooth surface in said contact opening from said first and second films in the opening.
2. A method according to claim 1 , wherein a fluorine compound is used as a reaction gas for the first etching, and a chlorine compound, a bromine compound, or a halide for forming said metal film is used as a reaction gas for the second etching.
3. A method according to claim 2 , wherein the fluorine compound is one compound selected from the group consisting of SF 6 , NF 3 and ClF 3 .
4. A method according to claim 2 , wherein the chlorine compound is one compound selected from the group consisting of HCl, Cl 2 and BCl 3 .
5. A method according to claim 2 , wherein the bromine compound is one compound selected from the group consisting of HBr, Br 2 and BBr 3 .
6. A method according to claim 1 , wherein a gas containing oxygen atoms or nitrogen atoms as a constituent element thereof is added as a gas for said second etching.
7. A method according to claim 6 , wherein the gas containing oxygen atoms or nitrogen atoms as a constituent element is oxygen or nitrogen gas.
8. A method according to claim 1 , wherein the etching reaction is an ion-sputter etching reaction and the deposition reaction is a bias-sputtering deposition reaction preformed in an ECR apparatus.
9. A method according to claim 1 , wherein the first film comprises TiON.
Cooperative Patent Classification codes for this invention. Click any code to explore related patents in that topic.
July 14, 1993
March 12, 2002
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