An information-recording medium comprising a substrate having thereon a recording layer capable of recording information with laser light, said recording layer containing: at least one compound selected from the group consisting of compounds represented by the following general formulae (I-1), (I-2), (I-3) and (I-4); and an organic dye other than said compounds. The symbols in the above formulae are defined in the specification.
Legal claims defining the scope of protection, as filed with the USPTO.
1. An information-recording medium comprising a substrate having thereon a recording layer capable of recording information with laser light, said recording layer containing: at least one compound selected from the group consisting of compounds represented by the following general formulae (I-1), (I-2), (I-3) and (I-4); and an organic dye other than said compounds: wherein A 1 , A 2 , B 1 and B 2 each independently represents a substituent; Y 1 and Z 1 each independently represents an atomic group necessary to form a carbocyclic or heterocyclic ring; E and G each independently represents an atomic group necessary to complete a conjugated double bond chain; X 1 represents O, NR or C(CN) 2 ; X 2 represents O, NR or C(CN) 2 (wherein R represents a substituent); L 1 , L 2 , L 3 , L 4 and L 5 each independently represents a methine group which may be substituted; m and n each independently represents 0, 1 or 2; x and y each independently represents 0 or 1; and K represents an integer needed to neutralize the charge of the counter cation; R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 each independently represents a hydrogen atom or a substituent (wherein each pair of R 1 and R 2 , R 3 and R 4 , R 5 and R 6 , and R 7 and R 8 may combine with each other to form a heterocyclic ring together with the nitrogen atom); R 9 , R 10 , R 11 , R 12 and R 13 each independently represents a substituent; p represents 1 or 2; and q and r each independently represents an integer of 0 to 4, and wherein said organic dye is an oxonol dye, and said oxonol dye is represented by the following general formula (II), wherein R 1 , R 2 , R 3 and R 4 each independently represents a hydrogen atom, an alkyl group, and aryl group, and aralkyl group or a heterocyclic group; L 1 , L 1 and L 3 each independently represents a methine group which may be substituted; m represents 0, 1, 2 or 3; and X k represents a cation wherein k represents an integer of 1 to 10.
2. The information-recording medium according to claim 1 , wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6, R 7 and R 8 in general formulae (I-1), (I-2), (I-3) and (I-4) each is a hydrogen or halogen atom, an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, an alkynyl group having 2 to 8 carbon atoms, an aryl group having 6 to 10 carbon atoms, an aralkyl group having 7 to 10 carbon atoms, or an alkoxy group having 1 to 8 carbon atoms.
3. The information-recording medium according to claim 1 , wherein X 1 is O and X 2 is O.
4. The information-recording medium according to claim 1 , wherein X k is a quaternary ammonium ion.
5. The information-recording medium according to claim 1 , wherein X k is an onium ion represented by the following general formula (II-1): wherein R 5 and R 6 each independently represents a substituent, R 7 and R 8 each independently represents an alkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group or a heterocyclic group; each pair of R 5 and R 6 , R 5 and R 7 , R 6 and R 8 , and R 7 and R 8 may connect each other to form a ring; r and s each independently represents an integer of 0 to 4; and when r and s are not smaller than 2, the plural R 5 's and R 6 's may be the same or different.
6. A method of recording optical information, comprising recording information on an information-recording medium by irradiating a laser light having a wavelength in a range of 750 to 850 nm or a range of 600 to 700 nm, wherein said information recording medium is an information-recording medium as claimed in any one of claims 1 to 3 , 7 or 8 .
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February 20, 2002
March 30, 2004
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